Chern, CY; Tseng, CC; Hsiao, RH; Wong, FF; Kuo, YH in [Chern, Ching-Yuh] Natl Chia Yi Univ, Dept Appl Chem, Chiayi 60004, Taiwan; [Tseng, Ching-Chun; Wong, Fung Fuh] China Med Univ, PhD Program Biotech Pharmaceut Ind, 91 Hsueh Shih Rd, Taichung 40402, Taiwan; [Hsiao, Rong-Hong; Wong, Fung Fuh] China Med Univ, Sch Pharm, 91 Hsueh Shih Rd, Taichung 40402, Taiwan; [Kuo, Yueh-Hsiung] China Med Univ, Dept Chinese Pharmaceut Sci & Chinese Med Resoure, Taichung 40402, Taiwan; [Kuo, Yueh-Hsiung] Asia Univ, Dept Biotechnol, Taichung 41354, Taiwan; [Kuo, Yueh-Hsiung] China Med Univ, Chinese Med Res Ctr, Taichung 40402, Taiwan published Cyclopentadienyl Ruthenium(II) Complex-Mediated Oxidation of Benzylic and Allylic Alcohols to Corresponding Aldehydes in 2019.0, Cited 60.0. Application In Synthesis of Benzyl Alcohol. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
This work reports an efficient method for the oxidation reaction of aliphatic, aromatic allylic, and benzylic alcohols into aldehydes catalyzed by the cyclopentadienyl ruthenium(II) complex (RuCpCl(PPh3)(2)) with bubbled O-2. Through further optimizing controlled studies, the tendency order of oxidation reactivity was determined as follows: benzylic alcohols>aromatic allylic alcohols>>aliphatic alcohols. In addition, this method has several advantages, including a small amount of catalyst (0.5mol%) and selective application of high discrimination activity of aliphatic, aromatic allylic, and benzylic alcohols.
Application In Synthesis of Benzyl Alcohol. Welcome to talk about 100-51-6, If you have any questions, you can contact Chern, CY; Tseng, CC; Hsiao, RH; Wong, FF; Kuo, YH or send Email.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles