An article Decarboxylation with Carbon Monoxide: The Direct Conversion of Carboxylic Acids into Potent Acid Triflate Electrophiles WOS:000463739900052 published article about FRIEDEL-CRAFTS ACYLATION; COUPLING REAGENTS; ACYL CHLORIDES; FUNCTIONALIZATION; CARBONYLATION; REARRANGEMENT; HALOGEN; KETONES; SALTS; CO in [Kinney, R. Garrison; Arndtsen, Bruce A.] McGill Univ, Dept Chem, 801 Sherbrooke St West, Montreal, PQ H3A 0B8, Canada in 2019.0, Cited 60.0. SDS of cas: 150-19-6. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6
We report a new strategy for the conversion of carboxylic acids into potent acid triflate electrophiles. The reaction involves oxidative carbonylation of carboxylic acids with I-2 in the presence of AgOTf, and is postulated to proceed via acyl hypoiodites that react with CO to form acid triflates. Coupling this chemistry with subsequent trapping with arenes offers a mild, room temperature approach to generate ketones directly from broadly available carboxylic acids without the use of corrosive and reactive Lewis or Bronsted acid additives, and instead from compounds that are readily available, stable, and functional group compatible.
SDS of cas: 150-19-6. About m-Methoxyphenol, If you have any questions, you can contact Kinney, RG; Arndtsen, BA or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles