Category: 141556-42-5

So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Thiess, Torsten; Mellerup, Soren K.; Braunschweig, Holger researched the compound: 1,3-Bis(2,4,6-trimethylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene( cas:141556-42-5 ).Application of 141556-42-5.They published the article 《B-B Cleavage and Ring-Expansion of a 1,4,2,3-Diazadiborinine with N-Heterocyclic Carbenes》 about this compound( cas:141556-42-5 ) in Chemistry – A European Journal. Keywords: diazadiborinine boron bond cleavage ring expansion imidazolylidene carbene; crystal structure diazadiborinine imidazolylidene complex diazadiborepine derivative; mol structure diazadiborinine imidazolylidene complex diazadiborepine derivative; B,N-heterocycles; B−B bond activation; NHCs; diazadiborinines; ring-expansion reactions. We’ll tell you more about this compound (cas:141556-42-5).

A 1,4,2,3-diazadiborinine derivative forms Lewis adducts with strong two-electron donors such as N-heterocyclic and cyclic (alkyl)(amino)carbenes. Depending on the donor, some of these Lewis pairs are thermally unstable, converting to sole B,N-embedded products upon gentle heating. The products of these reactions, which were fully characterized by NMR spectroscopy, elemental anal., and single-crystal x-ray diffraction, were identified as B,N-heterocycles with fused 1,5,2,4-diazadiborepine and 1,4,2-diazaborinine rings. Computational modeling of the reaction mechanism provides insight into the formation of these unique structures, suggesting that B-H, C-N, and B-B bond activation steps are responsible for these intercalation reactions between the 1,4,2,3-diazadiborinine and NHCs.

Different reactions of this compound(1,3-Bis(2,4,6-trimethylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)Application of 141556-42-5 require different conditions, so the reaction conditions are very important.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 141556-42-5, is researched, Molecular C21H24N2, about Solution processable metal-organic frameworks for mixed matrix membranes using porous liquids, the main research direction is solution processable metal organic framework matrix membrane porous liquid.Quality Control of 1,3-Bis(2,4,6-trimethylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene.

The combination of well-defined mol. cavities and chem. functionality makes crystalline porous solids attractive for a great number of technol. applications, from catalysis to gas separation However, in contrast to other widely applied synthetic solids such as polymers, the lack of processability of crystalline extended solids hampers their application. In this work, we demonstrate that metal-organic frameworks, a type of highly crystalline porous solid, can be made solution processable via outer surface functionalization using N-heterocyclic carbene ligands. Selective outer surface functionalization of relatively large nanoparticles (250 nm) of the well-known zeolitic imidazolate framework ZIF-67 allows for the stabilization of processable dispersions exhibiting permanent porosity. The resulting type III porous liquids can either be directly deployed as liquid adsorbents or be co-processed with state-of-the-art polymers to yield highly loaded mixed matrix membranes with excellent mech. properties and an outstanding performance in the challenging separation of propylene from propane. We anticipate that this approach can be extended to other metal-organic frameworks and other applications.

The article 《Solution processable metal-organic frameworks for mixed matrix membranes using porous liquids》 also mentions many details about this compound(141556-42-5)Quality Control of 1,3-Bis(2,4,6-trimethylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene, you can pay attention to it or contacet with the author([email protected]; [email protected]; [email protected]; [email protected]; [email protected]) to get more information.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Simple synthetic protocol to obtain 3d-4f-heterometallic carboxylate complexes of N-heterocyclic carbenes, published in 2020-08-01, which mentions a compound: 141556-42-5, mainly applied to transition metal tertbutylimidazolylidene bistrimethylphenylimidazolylidene complex preparation; crystal structure transition metal tertbutylimidazolylidene bistrimethylphenylimidazolylidene complex, Category: indole-building-block.

A new approach to NHC-substituted 3d-4f-heterometallic complexes is suggested based on coordination of the free NHC with a pre-organized carboxylate 3d-4f-core. Following this route, two novel complexes with different heterometallic cores, Co2La and Zn2Tb, have been prepared

The article 《Simple synthetic protocol to obtain 3d-4f-heterometallic carboxylate complexes of N-heterocyclic carbenes》 also mentions many details about this compound(141556-42-5)Category: indole-building-block, you can pay attention to it, because details determine success or failure

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 141556-42-5, is researched, Molecular C21H24N2, about Computational Exploration of Mechanistic Avenues in C-H Activation Assisted Pd-Catalyzed Carbonylative Coupling, the main research direction is bond activation palladium catalyzed carbonylative coupling aryl bromide polyfluoroarene.Related Products of 141556-42-5.

The detailed mechanism of the intermol. Pd-catalyzed carbonylative coupling reaction between aryl bromides and polyfluoroarenes relying on C(sp2)-H activation was investigated using state-of-the-art computational methods (SMD-B3LYP-D3(BJ)/BS2//B3LYP-D3/BS1). The mechanism unveils the necessary and important roles of a slight excess of carbon monoxide: acting as a ligand in the active catalyst state, participating as a reactant in the carbonylation process, and accelerating the final reductive elimination event. Importantly, the desired carbonylative coupling route follows the rate-limiting C-H activation process via the concerted metalation-deprotonation pathway, which is slightly more feasible than the decarboxylative route leading to byproduct formation by 1.2 kcal/mol. The analyses of the free energies indicate that the choice of base has a significant effect on the reaction mechanism and its energetics. The Cs2CO3 base guides the reaction toward the coupling route, whereas carbonate bases such as K2CO3 and Na2CO3 switch toward an undesired decarboxylative path. However, K3PO4 significantly reduces the C-H activation barrier over the decarboxylation reaction barrier and can act as a potential alternative base. The positional influence of a methoxy substituent in bromoanisole and different substituent effects in polyfluoroarenes were also considered. Our results show that different substituents impose significant impact on the desired carbonylative product formation energetics. Considering the influence of several ligands leads to the conclusion that other phosphine and N-heterocyclic carbene, such as PnBuAd2 and IMes, can be used as an efficient alternative than the exptl. reported PtBu3 ligand exhibiting a clear preference for C-H activation (ΔΔGLS) by 7.1 and 10.9 kcal/mol, resp. We have also utilized the energetic span model to interpret the exptl. results. Moreover, to elucidate the origin of activation barriers, energy decomposition anal. calculations were accomplished for the critical transition states populating the energy profiles.

The article 《Computational Exploration of Mechanistic Avenues in C-H Activation Assisted Pd-Catalyzed Carbonylative Coupling》 also mentions many details about this compound(141556-42-5)Related Products of 141556-42-5, you can pay attention to it, because details determine success or failure

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Fluorination Reactions at a Platinum Carbene Complex: Reaction Routes to SF3, S(O)F and Fluorido Complexes, published in 2021-12-15, which mentions a compound: 141556-42-5, mainly applied to mol structure optimized platinum carbene fluoro fluorosulfinyl trifluorosulfur complex; fluorination platinum carbene complex DFT oxidative addition sulfur tetrafluoride; platinum carbene fluoro fluorosulfinyl trifluorosulfur complex preparation; S−F activation; fluorido complexes; fluorine; platinum; sulfur fluorides, Related Products of 141556-42-5.

The electron-rich Pt complex [Pt(IMes)2] (IMes: [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolinylidine]) can be used as precursor for the syntheses of a variety of fluorido ligand containing compounds The sulfur fluoride SF4 undergoes a rapid oxidative addition at Pt0 to yield trans-[Pt(F)(SF3)(IMes)2]. A photolytic reaction of SF6 at [Pt(IMes)2] in the presence of IMes gave the fluorido complexes trans-[Pt(F)2(IMes)2] and trans-[Pt(F)(SF3)(IMes)2] along with trans-[Pt(F)(SOF)(IMes)2] and trans-[Pt(F)(IMes’)(IMes)] (IMes’: cyclometalated IMes ligand), the latter being products produced by reaction with adventitious water. Trans-[Pt(F)(SOF)(IMes)2] and trans-[Pt(F)2(IMes)2] were synthesized independently by treatment of [Pt(IMes)2] with SOF2 or XeF2. A reaction of [Pt(IMes)2] with a HF source gave trans-[Pt(H)(F)(IMes)2], and an intermediate bifluorido complex trans-[Pt(H)(FHF)(IMes)2] was identified. Compound trans-[Pt(H)(F)(IMes)2] converts in the presence of CsF into trans-[Pt(F)(IMes’)(IMes)].

The article 《Fluorination Reactions at a Platinum Carbene Complex: Reaction Routes to SF3, S(O)F and Fluorido Complexes》 also mentions many details about this compound(141556-42-5)Related Products of 141556-42-5, you can pay attention to it, because details determine success or failure

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 141556-42-5, is researched, Molecular C21H24N2, about Cationic Group VI Metal Imido Alkylidene N-Heterocyclic Carbene Nitrile Complexes: Bench-Stable, Functional-Group-Tolerant Olefin Metathesis Catalysts, the main research direction is molybdenum tungsten imido alkylidene NHC nitrile complex olefin metathesis; N-heterocyclic carbene; alkylidenes; metathesis; molybdenum; tungsten.Electric Literature of C21H24N2.

Despite their excellent selectivities and activities, Mo-and W-based catalysts for olefin metathesis have not gained the same widespread use as Ru-based systems, mainly due to their inherent air sensitivity. Herein, we describe the synthesis of air-stable cationic-at-metal molybdenum and tungsten imido alkylidene NHC nitrile complexes. They catalyze olefin metathesis reactions of substrates containing functional groups such as (thio-) esters, (thio-) ethers and alcs. without the need for prior activation, for example, by a Lewis acid. The presence of a nitrile ligand was found to be essential for their stability towards air, while no decrease in activity and productivity could be observed upon coordination of a nitrile. Variations of the imido and anionic ligand revealed that alkoxide complexes with electron-withdrawing imido ligands offer the highest reactivities and excellent stability compared to analogous triflate and halide complexes.

The article 《Cationic Group VI Metal Imido Alkylidene N-Heterocyclic Carbene Nitrile Complexes: Bench-Stable, Functional-Group-Tolerant Olefin Metathesis Catalysts》 also mentions many details about this compound(141556-42-5)Electric Literature of C21H24N2, you can pay attention to it, because details determine success or failure

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 141556-42-5, is researched, Molecular C21H24N2, about Cationic Group VI Metal Imido Alkylidene N-Heterocyclic Carbene Nitrile Complexes: Bench-Stable, Functional-Group-Tolerant Olefin Metathesis Catalysts, the main research direction is molybdenum tungsten imido alkylidene NHC nitrile complex olefin metathesis; N-heterocyclic carbene; alkylidenes; metathesis; molybdenum; tungsten.Electric Literature of C21H24N2.

Despite their excellent selectivities and activities, Mo-and W-based catalysts for olefin metathesis have not gained the same widespread use as Ru-based systems, mainly due to their inherent air sensitivity. Herein, we describe the synthesis of air-stable cationic-at-metal molybdenum and tungsten imido alkylidene NHC nitrile complexes. They catalyze olefin metathesis reactions of substrates containing functional groups such as (thio-) esters, (thio-) ethers and alcs. without the need for prior activation, for example, by a Lewis acid. The presence of a nitrile ligand was found to be essential for their stability towards air, while no decrease in activity and productivity could be observed upon coordination of a nitrile. Variations of the imido and anionic ligand revealed that alkoxide complexes with electron-withdrawing imido ligands offer the highest reactivities and excellent stability compared to analogous triflate and halide complexes.

The article 《Cationic Group VI Metal Imido Alkylidene N-Heterocyclic Carbene Nitrile Complexes: Bench-Stable, Functional-Group-Tolerant Olefin Metathesis Catalysts》 also mentions many details about this compound(141556-42-5)Electric Literature of C21H24N2, you can pay attention to it, because details determine success or failure

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Fluorination Reactions at a Platinum Carbene Complex: Reaction Routes to SF3, S(O)F and Fluorido Complexes, published in 2021-12-15, which mentions a compound: 141556-42-5, mainly applied to mol structure optimized platinum carbene fluoro fluorosulfinyl trifluorosulfur complex; fluorination platinum carbene complex DFT oxidative addition sulfur tetrafluoride; platinum carbene fluoro fluorosulfinyl trifluorosulfur complex preparation; S−F activation; fluorido complexes; fluorine; platinum; sulfur fluorides, Related Products of 141556-42-5.

The electron-rich Pt complex [Pt(IMes)2] (IMes: [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolinylidine]) can be used as precursor for the syntheses of a variety of fluorido ligand containing compounds The sulfur fluoride SF4 undergoes a rapid oxidative addition at Pt0 to yield trans-[Pt(F)(SF3)(IMes)2]. A photolytic reaction of SF6 at [Pt(IMes)2] in the presence of IMes gave the fluorido complexes trans-[Pt(F)2(IMes)2] and trans-[Pt(F)(SF3)(IMes)2] along with trans-[Pt(F)(SOF)(IMes)2] and trans-[Pt(F)(IMes’)(IMes)] (IMes’: cyclometalated IMes ligand), the latter being products produced by reaction with adventitious water. Trans-[Pt(F)(SOF)(IMes)2] and trans-[Pt(F)2(IMes)2] were synthesized independently by treatment of [Pt(IMes)2] with SOF2 or XeF2. A reaction of [Pt(IMes)2] with a HF source gave trans-[Pt(H)(F)(IMes)2], and an intermediate bifluorido complex trans-[Pt(H)(FHF)(IMes)2] was identified. Compound trans-[Pt(H)(F)(IMes)2] converts in the presence of CsF into trans-[Pt(F)(IMes’)(IMes)].

The article 《Fluorination Reactions at a Platinum Carbene Complex: Reaction Routes to SF3, S(O)F and Fluorido Complexes》 also mentions many details about this compound(141556-42-5)Related Products of 141556-42-5, you can pay attention to it, because details determine success or failure

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 141556-42-5, is researched, Molecular C21H24N2, about Computational Exploration of Mechanistic Avenues in C-H Activation Assisted Pd-Catalyzed Carbonylative Coupling, the main research direction is bond activation palladium catalyzed carbonylative coupling aryl bromide polyfluoroarene.Related Products of 141556-42-5.

The detailed mechanism of the intermol. Pd-catalyzed carbonylative coupling reaction between aryl bromides and polyfluoroarenes relying on C(sp2)-H activation was investigated using state-of-the-art computational methods (SMD-B3LYP-D3(BJ)/BS2//B3LYP-D3/BS1). The mechanism unveils the necessary and important roles of a slight excess of carbon monoxide: acting as a ligand in the active catalyst state, participating as a reactant in the carbonylation process, and accelerating the final reductive elimination event. Importantly, the desired carbonylative coupling route follows the rate-limiting C-H activation process via the concerted metalation-deprotonation pathway, which is slightly more feasible than the decarboxylative route leading to byproduct formation by 1.2 kcal/mol. The analyses of the free energies indicate that the choice of base has a significant effect on the reaction mechanism and its energetics. The Cs2CO3 base guides the reaction toward the coupling route, whereas carbonate bases such as K2CO3 and Na2CO3 switch toward an undesired decarboxylative path. However, K3PO4 significantly reduces the C-H activation barrier over the decarboxylation reaction barrier and can act as a potential alternative base. The positional influence of a methoxy substituent in bromoanisole and different substituent effects in polyfluoroarenes were also considered. Our results show that different substituents impose significant impact on the desired carbonylative product formation energetics. Considering the influence of several ligands leads to the conclusion that other phosphine and N-heterocyclic carbene, such as PnBuAd2 and IMes, can be used as an efficient alternative than the exptl. reported PtBu3 ligand exhibiting a clear preference for C-H activation (ΔΔGLS) by 7.1 and 10.9 kcal/mol, resp. We have also utilized the energetic span model to interpret the exptl. results. Moreover, to elucidate the origin of activation barriers, energy decomposition anal. calculations were accomplished for the critical transition states populating the energy profiles.

The article 《Computational Exploration of Mechanistic Avenues in C-H Activation Assisted Pd-Catalyzed Carbonylative Coupling》 also mentions many details about this compound(141556-42-5)Related Products of 141556-42-5, you can pay attention to it, because details determine success or failure

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Simple synthetic protocol to obtain 3d-4f-heterometallic carboxylate complexes of N-heterocyclic carbenes, published in 2020-08-01, which mentions a compound: 141556-42-5, mainly applied to transition metal tertbutylimidazolylidene bistrimethylphenylimidazolylidene complex preparation; crystal structure transition metal tertbutylimidazolylidene bistrimethylphenylimidazolylidene complex, Category: indole-building-block.

A new approach to NHC-substituted 3d-4f-heterometallic complexes is suggested based on coordination of the free NHC with a pre-organized carboxylate 3d-4f-core. Following this route, two novel complexes with different heterometallic cores, Co2La and Zn2Tb, have been prepared

The article 《Simple synthetic protocol to obtain 3d-4f-heterometallic carboxylate complexes of N-heterocyclic carbenes》 also mentions many details about this compound(141556-42-5)Category: indole-building-block, you can pay attention to it, because details determine success or failure

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles