Authors Roesel, AF; Ugandi, M; Huyen, NTT; Majek, M; Broese, T; Roemelt, M; Francke, R in AMER CHEMICAL SOC published article about CORRELATED MOLECULAR CALCULATIONS; C-H FUNCTIONALIZATION; GAUSSIAN-BASIS SETS; CHAIN PROCESSES; CONVERSION; OXIDATION; REDUCTION; PHENOLS; ELECTROSYNTHESIS; APPROXIMATIONS in [Ugandi, Mihkel; Roemelt, Michael] Ruhr Univ Bochum, Chair Theoret Chem, D-44780 Bochum, Germany; [Roesel, Arend F.; Nguyen Thi Thu Huyen; Majek, Michal; Broese, Timo; Francke, Robert] Rostock Univ, Inst Chem, D-18059 Rostock, Germany; [Nguyen Thi Thu Huyen] Hanoi Univ Sci & Technol, Sch Chem Engn, Hanoi, Vietnam; [Majek, Michal] Comenius Univ, Fac Nat Sci, Dept Organ Chem, Bratislava 84215, Slovakia in 2020.0, Cited 80.0. Quality Control of m-Methoxyphenol. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6
The facilitation of redox-neutral reactions by electrochemical injection of holes and electrons, also known as electrochemical catalysis, is a little explored approach that has the potential to expand the scope of electrosynthesis immensely. To systematically improve existing protocols and to pave the way toward new developments, a better understanding of the underlying principles is crucial. In this context, we have studied the Newman-Kwart rearrangement of O-arylthiocarbamates to the corresponding S-aryl derivatives, the key step in the synthesis of thiophenols from the corresponding phenols. This transformation is a particularly useful example because the conventional method requires temperatures up to 300 degrees C, whereas electrochemical catalysis facilitates the reaction at room temperature. A combined experimental-quantum chemical approach revealed several reaction channels and rendered an explanation for the relationship between the structure and reactivity. Furthermore, it is shown how rapid cyclic voltammetry measurements can serve as a tool to predict the feasibility for specific substrates. The study also revealed distinct parallels to photoredox-catalyzed reactions, in which back-electron transfer and chain propagation are competing pathways.
Quality Control of m-Methoxyphenol. Bye, fridends, I hope you can learn more about C7H8O2, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles