Category: 1912-47-6

Chemistry is traditionally divided into organic and inorganic chemistry. name: 2-(5-Methyl-1H-indol-3-yl)acetic acid. The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent，Which mentioned a new discovery about 1912-47-6

A stereoselective synthesis of functionalized hexahydrocarbazoles was developed based on an unprecedented photoredox-induced dearomative radical (4+2)-cyclization/1,4-addition cascade between 3-(2-iodoethyl)indoles and acceptor-substituted alkenes. The title reaction simultaneously generates three C?C bonds and one C?H bond, along with three contiguous stereogenic centers. The hexahydro-1H-carbazole products are highly valuable intermediates for the synthesis of novel antibiotics, as well as unnatural ring homologues of polycyclic indoline alkaloids.

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.name: 2-(5-Methyl-1H-indol-3-yl)acetic acid, you can also check out more blogs about1912-47-6

Reference：
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, Recommanded Product: 1912-47-6, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 1912-47-6, Name is 2-(5-Methyl-1H-indol-3-yl)acetic acid, molecular formula is C11H11NO2. In a Patent, authors is ，once mentioned of 1912-47-6

The present invention provides a substituted indole – 3 – acetic acid synthesis method, comprises the following steps: (1) in order to replace the indole as the starting material, with the acylation reagent under the action of catalyst through the tutor – acylation to obtain the 1, 3 – diacetyl substituted indole; (2) intermediate 1, 3 – diacetyl substituted indole does not need refining, directly with the morpholine and sulfur by the Willgerodt – Kindler rearrangement reaction, the inorganic under the catalysis of alkali hydrolysis, acidified to obtain substituted indole – 3 – acetic acid. (by machine translation)

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Reference：
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles