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TRIPHENYL MONOMERS SUITABLE FOR MICROSTRUCTURED OPTICAL FILMS

Optical films are described having a polymerized microstructured surface that comprises the reaction product of a polymerizable resin composition comprising at least one polymerizable ethylenically unsaturated triphenyl monomer. Also described are certain triphenyl (meth)acrylate monomers and polymerizable resin compositions.

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Reference£º
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

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TRIPHENYL MONOMERS SUITABLE FOR MICROSTRUCTURED OPTICAL FILMS

Optical films are described having a polymerized microstructured surface that comprises the reaction product of a polymerizable resin composition comprising at least one polymerizable ethylenically unsaturated triphenyl monomer. Also described are certain triphenyl (meth)acrylate monomers and polymerizable resin compositions.

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Reference£º
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Properties and Exciting Facts About tert-Butyl 4-(1H-indol-4-yl)piperazine-1-carboxylate

I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 252978-89-5, help many people in the next few years.COA of Formula: C17H23N3O2

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Hydrolytically stable pentaerythritol diphosphites

A class of hydrolytically stable bis(aralkylphenyl)pentaerythritol diphosphites is disclosed, which is suitable as an antioxidant additives in polyolefins, particularly, in polypropylene. The diphosphites are of low volatility, have a high thermal decomposition temperature and resist yellowing when blended into a polyolefin base. A preferred diphosphite is bis(2,4-dicumylphenyl)pentaerythritol diphosphite.

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Reference£º
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

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Mononuclear Salen-Sodium Ion Pairs as Catalysts for Isoselective Polymerization of rac-Lactide

A series of mononuclear salen-sodium anions, as the first examples, were synthesized with tetra-alkyl ammonium as a counterpart cation. These complexes are efficient catalysts for the isoselective ring-opening polymerization of rac-lactide; the molecular weights of polymers are under control and molecular weight distributions are narrow when five equivalents of BnOH is used as an initiator. The best isoselectivity value of Pm = 0.82 was achieved at -70 C. The experimental results together with a density functional theory calculation show that a ligand-assisted activated monomer mechanism is more reasonable than an activated monomer mechanism for this system.

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Reference£º
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

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Exploring steric effects in diastereoselective synthesis of chiral aminophenolate zinc complexes and stereoselective ring-opening polymerization of rac-lactide

A series of tridentate chiral aminophenol proligands and corresponding zinc complexes, LZnX (L = (S)-2-{[(1-R4-2-pyrrolidinyl)CH2N(R3)-]CH2}-6-R1-4-R2-C6H2O, X = N(SiMe3)2, R3 = nBu, R4 = Bn: R1 = R2 = Cl (1), R1 = R2 = Me (2), R1 = R2 = tBu (3); X = N(SiMe3)2, R1 = trityl, R2 = Me: R3 = n-octyl, R4 = Bn (4), R3 = Bn, R4 = Bn (5), R3 = nBu, R4 = naphthalen-1-ylmethyl (6), R3 = nBu, R4 = iPr (7); R1 = R2 = cumyl, R3 = Et, R4 = Bn: X = N(SiMe3)2 (8), X = OtBu (9), X = Et (10), X = Cl (11)), have been synthesized. Complexes 4, 6, and 11 were obtained as enantiopure products (4 and 6 as enantiopure a; 11 as enantiopure b), while complexes 1-3, 5, and 7-10 as a pair of diastereomers, but in different ratios, which have been proved by X-ray diffraction and NMR spectroscopic studies. When exposed to the ring-opening polymerization of rac-lactide, most of these complexes can effectively produce PLAs with narrow polydispersities, desirable molecular weights, and moderate to high isotacticities. The structure-selectivity relationships, including the relationships of structure-synthesis diastereoselectivity and structure-polymerization stereoselectivity, have been further investigated. Consistent trends of diastereoselectivity and stereoselectivity are observed with the variations of the R1 group at the ortho-position of the phenolate ring and the R3 group in the pyrrolidinyl moiety. The decrease of the steric bulkiness of the R4 group on the central amine has less influence on the diastereoselectivity, but leads to considerable loss of the stereoselectivity, whereas the decrease of the steric bulkiness of the X group results in a reverse of the diastereoselectivity, but shows no influence on the stereoselectivity. There is probably no direct relationship between the diastereoselectivity in complex synthesis and the stereoselectivity of the complex toward the ROP of rac-LA. The stereocontrol of these complexes might largely rely on the substituents in the ligand framework rather than their diastereomer ratios.

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Reference£º
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

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The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 252978-89-5 is helpful to your research. HPLC of Formula: C17H23N3O2

In homogeneous catalysis, the catalyst is in the same phase as the reactant. The number of collisions between reactants and catalyst is at a maximum.In a patent, 252978-89-5, name is tert-Butyl 4-(1H-indol-4-yl)piperazine-1-carboxylate, introducing its new discovery. HPLC of Formula: C17H23N3O2

Group 3 metal initiators with an [OSSO]-type bis(phenolate) ligand for the stereoselective polymerization of lactide monomers

A series of 1,Iomega-dithiaalkanediyl-bridged bis(phenols) of the general type [OSSO]H2 with variable steric properties and various bridges were prepared. The stoichiometric reaction of the bis(phenols) 1,3-dithiapropanediyl-2,2′-bis(4,6-di-tert-butylphenol), 1,3-dithiapropanediyl- 2,2′-bis[4,6-di(2-phenyl-2-propyl)phenol], rac-2,3-trans-propanediyl-1,4- dithiabutanediyl-2,2′-bis[4,6-di(2-phenyl-2-propyl)phenol], rac-2,3-trans- butanediyl-1,4-dithiabutane diyl-2,2′-bis[4,6-di(2-phenyl-2-propyl)phenol], rac-2,3-trans-hexanediyl-1,4-dithiabutanediyl-2,2′-bis[4,6-di(2-phenyl-2-propyl) phenol], 1,3-dithiapropanediyl-2,2′-bis[6-(1-methylcyclohexyl)-4-methylphenol] (C1, R=1-methylcyclohexyl), and 1,4-dithiabutanediyl-2,2′-bis[6-(1- methylcyclohexyl)-4-methylphenol] with rare-earth metal silylamido precursors [Ln{N(SiHMe2)2}3(thf)x] (Ln=Sc, x=1 or Ln=Y, x=2; thf=tetrahydrofuran) afforded the corresponding scandium and yttrium bis(phenolate) silylamido complexes [Ln(OSSO){N(SiHMe2) 2}(thf)] in moderate to good yields. The monomeric nature of these complexes was shown by an X-ray diffraction study of one of the yttrium complexes. The complexes efficiently initiated the ring-opening polymerization of rac- and meso-lactide to give heterotactic-biased poly(rac-lactides) and highly syndiotactic poly(meso-lactides). Variation of the ligand backbone and the steric properties of the ortho substituents affected the level of tacticity in the polylactides. Copyright

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Reference£º
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Brief introduction of tert-Butyl 4-(1H-indol-4-yl)piperazine-1-carboxylate

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A method for preparing 2, 4, 6 – dicumylic (by machine translation)

A 2, 4, 6 – dicumylic preparation method, which relates to a 2, 4, 6 – dicumylic preparation method. The method of the invention is: nitrogen protection, under a certain temperature, the reaction of the phenol with a catalytic amount of the aluminum powder, aluminum powder completely disappeared after to, add a certain amount of ionic liquid is used as the cocatalyst, then adding alpha – methyl styrene, high performance liquid chromatography monitoring reaction, when the 2, 4, 6 – three dry bases phenol content when not continue to increase, adding dilute sulfuric acid to terminate the reaction, toluene extraction reaction product, atmospheric distillation to remove trace water in toluene, after cooling has white crystals, filtering to obtain the crude product; the crude product is then carried out for the 2nd toluene recrystallization to obtain content is more than 99% of the 2, 4, 6 – three dry bases phenol. This preparation method yield 64% the left and the right. Then the recrystallization mother liquor after removing the solvent, added with a certain amount of the phenol compound catalyst, continue to reaction, the mother liquor after the recovery, to the total amount is calculated, a yield of 95% or more. (by machine translation)

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Reference£º
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Extended knowledge of tert-Butyl 4-(1H-indol-4-yl)piperazine-1-carboxylate

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Novel alkoxo-titanium(IV) complexes with fluorinated 2-hydroxymethylphenol derivatives as catalysts for the formation of ultra-high molecular weight polyethylene nascent reactor powders

A series of titanium (IV) complexes 3a?g stabilized by fluorinated derivatives of 2-hydroxymethylphenol have been synthesized; their composition and structure have been confirmed by NMR, IR-spectroscopy and elemental analysis. The structures of compounds 3c, 3f and 3g have been unambiguously established by X-ray diffraction study. The complexes in the presence of a binary cocatalysts {alkyl aluminum chloride + MgBu2} catalyze ethylene polymerization to afford Ultra High Molecular Weight Polyethylene (UHMWPE). The effects of substituents in the ligands on the catalytic activity and properties of the obtained polymer ? molecular weight, DSC melting behavior, and morphology of nascent reactor powders have been investigated. UHMWPE samples were processed by a solid-state uniaxial deformation into high-strength (up to 2.65 GPa) and high-modulus (over 140 GPa) oriented film tapes, which indirectly indicates a low degree of entanglements between the macromolecular chains.

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Reference£º
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

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A lanostane aldehyde from Momordica charantia

A new lanostane aldehyde, charantal (1), was isolated from the ethanolic leaf extract of Momordica charantia together with the known compound, 2,4-bis(2-phenylpropan-2-yl)phenol (2). The structure of compound 1 was elucidated by extensive 1D and 2D NMR and MS experiments. Compound 2 displayed a moderately strong antitubercular activity against Mycobacterium tuberculosis H37Rv (MIC = 14 mug/mL) according to the MABA susceptibility assay.

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Reference£º
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

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An asymmetric nitrogen-oxygen ligand and Ti, Zr, Hf complex preparation method and application (by machine translation)

The invention discloses an asymmetric nitrogen-oxygen ligand and Ti, Zr, Hf complex preparation method and application. The complex preparation method comprises the following steps: in order to replace salicyldehyde and 2-ammonia methylpyridinio and containing different substituents shall phenol system asymmetric nitrogen-oxygen ligand; and the asymmetric nitrogen-oxygen ligand TiCl 4, ZrCl 4, HfCl 4 the reaction is carried out in toluene, containing asymmetric nitrogen oxygen multi-teeth ligand is Ti, Zr, Hf complex. This kind of complex is mainly used for ring-opening polymerization of lactide, has a high catalytic activity and good stereoselectivity. The ligand of this invention and Ti, Zr, Hf complex, easy availability of raw materials, the preparation method is simple, the structure is easy to modulation, ligand construction through the change, can adjust and control the nature of the complex, improve its catalytic performance, can be used for preparing molecular weight distribution is relatively narrow, the stereo regular the high molecular material of biodegradation and polylactide, is suitable for popularization. (by machine translation)

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Reference£º
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles