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Process for dyeing human keratinous fibres, consisting in applying on these fibres at least least one composition (A) containing, in a cosmetically acceptable medium, one or more indole derivatives corresponding to the formula (I) STR1 in which: R1 denotes a hydrogen atom, a lower C1 -C6 lower akly group or a group –SiR9 R10 R11 ; R2 and R3, which may be identical or different, denote a hydrogen atom, a C1 -C6 lower alkyl group, a carboxyl group, a lower alkoxycarbonyl group wherein the alkoxy moiety contains 1 to 6 carbon atoms, or a group –COOSiR9 R10 R11 ; R4 and R5, which may be identical or different, denote a hydrogen atom, a C1 -C20 linear or branched alkyl group, a formyl group, a linear or branched C2 -C20 acyl group, a linear or branched C3 -C20 alkenoyl group, a group –SiR9 R10 R11, a group –P(O) (OR6)2 or a group R6 OSO2 –, or alternatively R4 and R5, together with the oxygen atoms to which they are attached, form a ring optionally containing a carbonyl group, a methylene group, a thiocarbonyl group or one of the following groups; >P(O)OR6, or >CR7 R8 ; R6 and R7 denoting a hydrogen atom or C1 -C6 lower alkyl group, R8 denoting a C1 -C6 lower alkoxy group or a mono- or di-C1 -C6 alkylamino group, R9,R10 and R11, which may be identical or different, denoting C1 -C6 linear or branched alkyl groups, and the corresponding salts of alkali metals, alkaline-earth metals and amines, at least one of the radicals R1 to R5 being other than hydrogen, in combinations: either (a) with iodide ions, or (b) with a solution of hydrogen peroxide at a pH of between 3.5 and 7, the application of the composition (A) being preceded or followed by the application of composition (B) which contains, in a cosmetically acceptable medium, either (a) hydrogen peroxide at a pH of between 2 and 7 when the composition (A) contains iodide ions, or (b) iodide ions when the composition (A) contains hydrogen peroxide.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles