88-15-3 | - Indole Building Blocks

Brief introduction of C6H6OS

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In an article, author is Cera, Gianpiero, once mentioned the application of 88-15-3, Formula: https://www.ambeed.com/products/88-15-3.html, Name is 1-Thiophen-2-yl-ethanone, molecular formula is C6H6OS, molecular weight is 126.18, MDL number is MFCD00005442, category is indole-building-block. Now introduce a scientific discovery about this category.

The combination of a Pd(0) complex with benzoic acid converts propargylic tryptamines to the corresponding tetrahydro-beta-carbolines. The method uses unprotected indoles and affords the desired products with ample functional group tolerance. Detailed modeling studies reveal a close synergy between the organic and metal catalysts, which enables sequential alkyne isomerization, indole C-H activation, and eventual C-C reductive elimination to afford the target heterocycles.

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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Properties and Exciting Facts About 88-15-3

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88-15-3, Name is 1-Thiophen-2-yl-ethanone, molecular formula is C6H6OS, Computed Properties of C6H6OS, belongs to indole-building-block compound, is a common compound. In a patnet, author is Bachmann, Philipp, once mentioned the new application about 88-15-3.

Dehydrogenation of the Liquid Organic Hydrogen Carrier System Indole/Indoline/Octahydroindole on Pt(111)

Indole derivatives are considered as promising liquid organic hydrogen carriers for renewable energy storage. Using X-ray photoelectron spectroscopy, temperature-programmed desorption, and infrared reflection absorption spectroscopy, we investigated low-temperature adsorption and dehydrogenation during heating of indole, indoline, and octahydroindole on Pt(111). For all three molecules, we find deprotonation of the NH bond above 270 K, accompanied with dehydrogenation of indoline and octahydroindole via an indole intermediate, resulting in an indolide species above 300 K. For octahydroindole, we also find a side reaction yielding small amounts of a pi-allyl species between 170 and 450 K. Above 450 K, decomposition of the remaining indolide species takes place.

Reference:
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

What I Wish Everyone Knew About 88-15-3

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One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, such as the rate of change in the concentration of reactants or products with time. 88-15-3, Name is 1-Thiophen-2-yl-ethanone, formurla is C6H6OS. In a document, author is Ji, Yuan-Zhao, introducing its new discovery. Recommanded Product: 88-15-3.

Regioselective and oxidant-free sulfinylation of indoles and pyrroles with sulfinamides

An unexpected time-controlled highly selective C3-or C2-sulfinylation of pyrroles with sulfinamides is reported for the first time. The sulfinylation of indoles with sulfinamides using this protocol is oxidant-free and can be performed under obviously more feasible conditions (1.2 equiv. of indoles, 10 min) in comparison with the precedent procedure (3-20 equiv. of indoles, 16-18 h, ammonium persulfate as oxidant, hv). A variety of functional groups were tolerated, and various C2-thioindoles and C2/ 3-thiopyrroles were obtained in moderate to excellent yields.