Palladium Nanoparticles in Glycerol: A Versatile Catalytic System for C-X Bond Formation and Hydrogenation Processes was written by Chahdoura, Faouzi;Pradel, Christian;Gomez, Montserrat. And the article was included in Advanced Synthesis & Catalysis in 2013.Related Products of 118-12-7 This article mentions the following:
Palladium nanoparticles stabilized by tris(3-sulfophenyl)phosphine trisodium salt in neat glycerol have been synthesized starting from both Pd(II) and Pd(0) species and fully characterized. The versatility of this innovative catalytic colloidal solution has been proved by its efficient application in C-X bond formation processes (X = C, N, P, S) and C-C multiple bond hydrogenation reactions. The catalytic glycerol phase could be recycled more than ten times, preserving its activity and selectivity. The scope of each of these processes has demonstrated the power of the as-prepared catalyst, isolating the corresponding expected products in yields higher than 90%. The dual catalytic behavior of this glycerol phase, associated to the metallic nanocatalysts used in wet medium (mol.- and surface-like behavior), has allowed attractive applications in one-pot multi-step transformations catalyzed by palladium, such as C-C coupling followed by hydrogenation, without isolation of intermediates using only one catalytic precursor. In the experiment, the researchers used many compounds, for example, 1,3,3-Trimethyl-2-methyleneindoline (cas: 118-12-7Related Products of 118-12-7).
1,3,3-Trimethyl-2-methyleneindoline (cas: 118-12-7) belongs to indole derivatives. Indole produced by Proteus, Pseudomonas, Escherichia and other species was shown to be a growth promoting factor in Arabidopsis thaliana. In addition to indole, the strain-release chemistry worked for numerous substrates including amines, alcohols, thiols, carboxylic acids, imidazoles, and pyrazoles.Related Products of 118-12-7
Referemce:
Indole alkaloid derivatives as building blocks of natural products from聽Bacillus thuringiensis聽and聽Bacillus velezensis聽and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles