Product Details of 100-51-6. In 2019.0 INORG CHEM published article about PHOTOLUMINESCENCE PROPERTIES; STRUCTURAL-CHARACTERIZATION; MOLECULAR-STRUCTURE; COMPLEXES; LIGANDS; CU(I); BR; NANOCLUSTER; CHEMISTRY; CRYSTAL in [Pillay, Michael N.; van Zyl, Werner E.] Univ KwaZulu Natal, Sch Chem & Phys, Westville Campus, ZA-4000 Durban, South Africa; [Liao, Jian-Hong; Liu, C. W.] Natl Dong Hwa Univ, Dept Chem, Hualien 97401, Taiwan in 2019.0, Cited 49.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
A series of seven luminescent copper(I) dithiophosphonate (dtp) clusters of the type Cu4L4 (L = S2PR(OR’)(-)) were formed from CuCl2 center dot 2H(2)O precursor in aqueous medium under ambient conditions. The dtp ligand serves the dual function of acting as a sacrificial reducing agent and cluster core stabilizer. The new clusters were characterized by H-1 and P-31 NMR and ESI-MS, and the single-crystal X-ray structures for two representative clusters [Cu-4{(S2P(1,4-C6H4OMe)(OR’)}4] (R’ = OCH(CH3)(2); CH2C6H5) were determined. The redox reaction yielded clusters in satisfactory yield, and all exhibited luminescence with lambda(em)(max) in the range 519-534 nm and half-lives in the range 10-14 mu s.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles