Recently I am researching about SEQUENTIAL THERMAL DISSOLUTION; CATALYZED OXIDATION; MILD DEGRADATION; BITUMINOUS COAL; EXTRACTION; IDENTIFICATION; ALKYLBENZENES; FEATURES; ORIGIN; BONDS, Saw an article supported by the Fundamental Research Funds for the Central Universities of ChinaFundamental Research Funds for the Central Universities [2018QNA15]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2018M630630]. Category: indole-building-block. Published in ELSEVIER SCI LTD in OXFORD ,Authors: Liu, FJ; Zong, ZM; Li, WT; Zhu, XN; Wei, XY; Tang, MC; Huang, ZX. The CAS is 100-51-6. Through research, I have a further understanding and discovery of Benzyl Alcohol
Converting lignite into soluble organic compounds (SOCs) under mild conditions is significant for both evaluating molecular structure and producing clean fuels/chemicals. A three-step dissociation, i.e., sequential extraction, sequential thermal dissolution (TD), and ruthenium-ion-catalyzed oxidation (RICO), was adopted to convert the organic matter (OM) in Xiaolongtan lignite (XL) into SOCs. The perspectives on chemicals, geo-chemical information, and structural characteristics of XL were evaluated based on the molecular compositions of SOCs. Much higher yields of SOCs were obtained from TD than from extraction, which could be attributed to the thermal dissociation of non-covalent interactions in XL. Normal alkanes, alkyl-substituted benzenes, alkyl substituted phenols, ketones, and aliphatic esters are the main group components released from TD. A series of important biomarkers were released and their distributions and evolution pathways during XL-forming process imply that higher terrestrial plants could be the main input of the OM in XL. Benzenecarboxylic acids were produced from TD residue in high selectivity via the RICO. According to the results from the RICO, the insoluble macromolecular structures in XL are rich in peri-condensed aromatics along with some cata-condensed aromatics and polyaryls, and -CH3 is the major alkyl side chain on the aromatic rings. Adjacent aromatic moieties are mainly connected each other directly by C-ar-C-ar bridged bonds.
Category: indole-building-block. About Benzyl Alcohol, If you have any questions, you can contact Liu, FJ; Zong, ZM; Li, WT; Zhu, XN; Wei, XY; Tang, MC; Huang, ZX or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles