Name: Benzyl Alcohol. In 2019.0 J IND ENG CHEM published article about HIV-1 PROTEASE INHIBITORS; SELECTIVE HYDROGENATION; PHOTOCATALYTIC REDUCTION; TIO2 NANOPARTICLES; HIGHLY EFFICIENT; BENZALDEHYDE; CATALYSTS; PERFORMANCE; STABILITY; ARRAYS in [Aulakh, Manpreet Kaur; Pal, Bonamali] Thapar Inst Engn & Technol, Sch Chem & Biochem, Patiala 147004, Punjab, India in 2019.0, Cited 42.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
Mono-dispersed and smaller sized TiO2 nanospheres C8 nm and 20 nm) exhibited superior photo-reductive efficiency for few aromatic aldehydes under UV light. It has been found that p-nitrobenzaldehyde and benzaldehyde are efficiently reduced to p-aminobenzyl alcohol (80% and 61%) and benzyl alcohol (59% and 38%) by 8 nm and 20 nm particles respectively, relative to negligible reduction by TiO2 (P25) under same experimental conditions. However, the successful photo-reduction of p-nitrotoluene (97%) was observed with P25 whose reduction potential (-0.5 eV) lies below the conduction band (CB, -0.85 eV vs NHE) of the catalyst. These findings can be explained on the basis of unsuitable and mismatched CB of P25 with respect to the lowest unoccupied molecular orbital of -CHO group to access its photo-activity. However, this hydrogenation occurred by synthesized smaller sized TiO2 particles (8 nm and 20 nm) due to their favorable band gap (3.85 eV and 3.62 eV) and conduction band edge (-0.61 eV and -0.50 eV). Moreover, the other physio-chemical characteristics of 8 nm and 20 nm sized particles such as surface area (323 m(2)g(-1), and 297 m(2)g(-1)), higher charge carrier relaxation time (61 mu s and 40 mu s) are also co-related for ease of photo-activity relative to TiO2 (P25). (C) 2019 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles