Recently I am researching about PYRROLIDINES, Saw an article supported by the Laboratory of Excellence in Research on Medication and Innovative Therapeutics (LERMIT) [ANR-10-LABX-33, ANR-11-IDEX-0003-01]; SATT Paris-Saclay (project CARBAMAT); CNRSCentre National de la Recherche Scientifique (CNRS)European Commission; Universite Paris-Saclay; ICSN. Product Details of 123-11-5. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: D’Hollander, ACA; Romero, E; Vijayakumar, K; Le Houerou, C; Retailleau, P; Dodd, RH; Iorga, BI; Cariou, K. The CAS is 123-11-5. Through research, I have a further understanding and discovery of 4-Methoxybenzaldehyde
Under basic conditions and heat, ynamides can serve as precursors to ketenimines, whose synthetic potential is often hampered by their difficulty of access. Herein, we report that they can undergo a [3+2] cycloaddition with 2-azaallyl anions, obtained from benzylimines under the same reaction conditions. This reaction between two highly reactive intermediates, both generated in situ from bench stable starting materials, gives access to various nitrogen-rich heterocycles. The reaction usually proceeds with excellent diastereoselectivity, in favor of the cis adduct. Deuteration experiments and DFT calculations helped rationalize the regio- and stereoselectivity of the process as well as the formation of side products.
Product Details of 123-11-5. About 4-Methoxybenzaldehyde, If you have any questions, you can contact D’Hollander, ACA; Romero, E; Vijayakumar, K; Le Houerou, C; Retailleau, P; Dodd, RH; Iorga, BI; Cariou, K or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles