Authors Jin, JK; Zheng, WX; Xia, HM; Zhang, FL; Wang, YF in AMER CHEMICAL SOC published article about HETEROCYCLIC CARBENE BORANES; FLUORINE; ALKENES; BORON; HYDRODEFLUORINATION; CYCLIZATIONS; CATALYSIS; ARYNES; AMINE in [Jin, Ji-Kang; Zheng, Wan-Xin; Xia, Hui -Min; Zhang, Feng-Lian; Wang, Yi-Feng] Univ Sci & Technol China, Ctr Excellence Mol Synth CAS, Hefei Natl Lab Phys Sci Microscale, 96 Jinzhai Rd, Hefei 230026, Anhui, Peoples R China; [Jin, Ji-Kang; Zheng, Wan-Xin; Xia, Hui -Min; Zhang, Feng-Lian; Wang, Yi-Feng] Univ Sci & Technol China, Dept Chem, 96 Jinzhai Rd, Hefei 230026, Anhui, Peoples R China; [Wang, Yi-Feng] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China in 2019.0, Cited 57.0. Formula: C7H6O2. The Name is 3-Hydroxybenzaldehyde. Through research, I have a further understanding and discovery of 100-83-4
A regioselective radical hydroboration of gem-difluoroalkenes was developed for the synthesis of alpha-difluoroalkylborons. The reaction features excellent regioselectivity, broad substrate scope, and good functional group capability. DFT calculations implicated the remarkable alpha-selectivity was driven from the kinetically and thermodynamically more favorable alpha-addition step. The resulting alpha-difluoroalkylborons could be readily converted into NHC-boranetethered monofluoroalkenes, which demonstrated unique reactivity and applicability in the synthesis of monofluoroalkene derivatives through transformations of the boron unit.
Formula: C7H6O2. Welcome to talk about 100-83-4, If you have any questions, you can contact Jin, JK; Zheng, WX; Xia, HM; Zhang, FL; Wang, YF or send Email.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles