An article Nanostructured thermosets involving epoxy and poly(ionic liquid)-Containing diblock copolymer WOS:000608415300002 published article about IONIC LIQUID; BLOCK-COPOLYMERS; RESIN; POLYMERIZATION; CRYSTALLIZATION; BLENDS; SEPARATION; CONVERSION; MEMBRANES; ANION in [Zheng, Sixun] Shanghai Jiao Tong Univ, Coll Chem & Chem Engn, Shanghai 200240, Peoples R China; Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China in 2021.0, Cited 50.0. Application In Synthesis of Benzyl Alcohol. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
A novel poly(ionic liquid) (PIL)-containing diblock copolymer was synthesized via a sequential living/controlled polymerization approach. First, the ring-opening polymerization of epsilon-caprolactone (CL) was carried out to obtain a monohydroxyl-terminated PCL. The terminal hydroxyl group of the PCL chain was then exploited to react with carboxyl group of 2-(dodecylthiocarbonothioylthio)-2-methylpropanoic acid to obtain a trithiocarbonate-terminated PCL. Thereafter, such trithiocarbonate-terminated PCL was used to mediate the radical polymerization of tri-n-butyl-(4-vinylbenzyl) phosphoniumbis(trifluoromethane)sulfonamide (TBP+-TFSI-) to afford PIL diblock copolymers. Notably, the PIL diblock copolymers are capable of displaying self-assembly behavior in selective solvent (e.g., ethyl acetate). In the suspensions of ethyl acetate, the self-assembly generated the spherical micelles with the aggregates of P(TBP+-TFSI-) as the cores and with PCL blocks as the coronas. Such a self-assembly behavior was further employed to obtain epoxy thermoset with nanostructures. Owing to the introduction of fluorine-containing PIL diblock copolymer, the surface dewettability of the thermosets was significantly improved owing to the enrichment of P(TBP+-TFSI-) at the surface. The introduction of PIL microdomains in epoxy resulted that the dielectric constants of the materials were significantly enhanced. More importantly, the dielectric constants were temperature-dependent and can be further enhanced while the nanostructured thermosets were heated above the glass transition temperature of PIL blocks.
Application In Synthesis of Benzyl Alcohol. About Benzyl Alcohol, If you have any questions, you can contact Adeel, M; Zhao, BJ; Mei, HG; Li, L; Zheng, SX or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles