Mega, Riccardo S.; Duong, Vincent K.; Noble, Adam; Aggarwal, Varinder K. published the article 《Decarboxylative Conjunctive Cross-coupling of Vinyl Boronic Esters using Metallaphotoredox Catalysis》. Keywords: photochem decarboxylative borylation arylation carboxylic acid preparation benzylboronic ester; photocatalyst organocatalyst decarboxylation borylation arylation carboxylic acid preparation benzylboronate; alkyl boronic esters; carboxylic acids; conjunctive cross-coupling; decarboxylative cross-coupling; metallaphotoredox catalysis.They researched the compound: Nickel(II) chloride ethylene glycol dimethyl ether complex( cas:29046-78-4 ).Recommanded Product: 29046-78-4. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:29046-78-4) here.
Photochem. decarboxylation, arylation and borylation of carboxylic acids and α-amino acids catalyzed by 1,2,3,5-tetracarbazolyl. The synthesis of complex alkyl boronic esters through conjunctive cross-coupling of vinyl boronic esters with carboxylic acids and aryl iodides is described. The reaction proceeds under mild metallaphotoredox conditions and involves an unprecedented decarboxylative radical addition/cross-coupling cascade of vinyl boronic esters. Excellent functional-group tolerance is displayed, and application of a range of carboxylic acids, including secondary α-amino acids, and aryl iodides provides efficient access to highly functionalized alkyl boronic esters. The decarboxylative conjunctive cross-coupling was also applied to the synthesis of sedum alkaloids.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
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