The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Nickel(II) chloride ethylene glycol dimethyl ether complex, is researched, Molecular C4H10Cl2NiO2, CAS is 29046-78-4, about Versatile Production of Novel PNP Based Metal Complexes Applicable as Water Reduction Catalysts Showing CH/M as Well as CH/π Interactions, the main research direction is bis dianisylphosphanylmethyl alkylamine preparation crystal mol structure complexation; PNP metal complex preparation reduction catalyst mol structure calculation.HPLC of Formula: 29046-78-4.
Several PNP-type ligands of the form bis(dianisylphosphanylmethyl)alkylamine, where alkyl is Me, Et, iso-Pr, and benzyl (1-4), have been coordinated to Co(II), Ni(II), Pd(II), and Pt(II) (5-26). This series of water reduction catalysts (WRC) has been characterized by single-crystal x-ray structure anal., multinuclear and 2D NMR spectroscopy, mass spectrometry and a computational study. Intramol. contact approaches show differences depending on hetero- or homoleptic complexes. Both solid state and solution structures indicate an enhancement of steric pressure for the latter. As a consequence CH/M as well as CH/π interactions appear in the x-ray structures and 1H NMR spectra. They can also be clearly identified by quantum mech. calculations on a B3LYP level. Since these WRC contain proton relays due to the used PNP-ligands, they are prone to proton coupled electron transfer (PCET) during photocatalysis. The different steric pressure influences their reorganization energy. Obviously, the observed intramol. contact approaches should be regarded as a tool for the design of future WRC.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
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