Recently I am researching about SECONDARY PHOSPHINE OXIDES; CHEMOSELECTIVE HYDROGENATION; ALPHA,BETA-UNSATURATED KETONES; NANOPARTICLES; SEMIHYDROGENATION; ACTIVATION; CONVERSION; ALKENES; ALKYNES; CARBON, Saw an article supported by the INCT-Catalise; Brazilian government agency FAPESP [2016/16738-7]; Brazilian government agency CNPqConselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPQ); Brazilian government agency CAPESCoordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES). Published in SOC BRASILEIRA QUIMICA in SAO PAULO ,Authors: Silva, RJM; Fiorio, JL; Vidinha, P; Rossi, LM. The CAS is 100-51-6. Through research, I have a further understanding and discovery of Benzyl Alcohol. HPLC of Formula: C7H8O
Gold catalysts are best known for their selectivity in oxidation reactions, however, there is a promising future for gold in selective hydrogenations. Herein, the hydrogenation of several aldehydes and important bio-based chemical building blocks, namely 5-hydroxymethylfurfural (5-HMF), furfural and vanillin, was performed throughout the combination of Au nanoparticles with Lewis bases. The Au-amine ligand (e.g.. 2,4,6-trimethylpyridine) catalytic system could reduce the aldehyde carbonyl group selectively, without reducing alkene moieties or opening the furanic ring that occur on most traditional catalysts. Otherwise, the reduction of nitro group is preferential and the catalytic system was used for the synthesis of furfurylamines, important intermediates in the synthesis of different pharmaceuticals (e.g., furosemide), through the selective reductive amination of furfural starting from nitro-compounds. Moreover, a fully heterogeneous gold catalyst embedded in N-doped carbon (Au@N-doped carbon/TiO2) was able to perform these reactions in successive recycles without the addition of ligands, with impact in the development of a continuous flow process for biomass valorization.
HPLC of Formula: C7H8O. Bye, fridends, I hope you can learn more about C7H8O, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles