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A convenient and efficient approach for the synthesis of 2,3-dihydro-2,3?-bisindoles has been developed in good yields via dimerization of N-H indole derivatives. The synthetic utility of this approach was demonstrated by the rapid construction of bisindoles in gram-scale. Biological evaluation revealed that some of the obtained 2,3-dihydro-2,3?-bisindoles exhibited significant in vitro antiproliferative activities on human-derived lung, liver, stomach, and breast cancer cell lines.
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Reference：
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles