Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 62613-82-5, Name is Oxiracetam(Random Configuration), SMILES is O=C(N)CN1C(CC(O)C1)=O, in an article , author is Cirujano, Francisco G., once mentioned of 62613-82-5, Application In Synthesis of Oxiracetam(Random Configuration).
MOFs Extend the Lifetime of Pd(II) Catalyst for Room Temperature Alkenylation of Enamine-Like Arenes
The synthesis of pharmaceutically relevant scaffolds, such as substituted indoles or uracils, through the alkenylation of the enamine-like aromatic C-H bond is performed at room temperature using catalytic amounts of Pd(OAc)(2) in the presence of redox active, stable and reusable metalorganic microporous frameworks. This is the first time that redox/acid active sites in the porous, nontoxic and earth abundant robust MOF-74 platform are used to avoid the fast deactivation of the cationic Pd species working under ambient conditions.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles