An article Efficient methylation of anilines with methanol catalysed by cyclometalated ruthenium complexes WOS:000639998200015 published article about HYDROGEN-TRANSFER REDUCTION; MONO-N-METHYLATION; BORROWING HYDROGEN; PINCER RUTHENIUM; OS COMPLEXES; AMINES; KETONES; LIGANDS; RU; HETEROCYCLES in [Piehl, Patrick; Amuso, Roberta; Spannenberg, Anke; Neumann, Helfried; Beller, Matthias] Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany; [Amuso, Roberta; Gabriele, Bartolo] Univ Calabria, Dept Chem & Chem Technol, Lab Ind & Synthet Organ Chem LISOC, Via Pietro Bucci 12-C, I-87036 Arcavacata Di Rende, CS, Italy in 2021.0, Cited 63.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6. Formula: C7H8O
Cyclometalated ruthenium complexes 4-10 allow the effective methylation of anilines with methanol to selectively give N-methylanilines. This hydrogen autotransfer procedure proceeds under mild conditions (60 degrees C) in a practical manner (NaOH as base). Mechanistic investigations suggest an active homogenous ruthenium complex and beta-hydride elimination of methanol as the rate determining step.
About Benzyl Alcohol, If you have any questions, you can contact Piehl, P; Amuso, R; Spannenberg, A; Gabriele, B; Neumann, H; Beller, M or concate me.. Category: indole-building-block
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles