Downstream Synthetic Route Of 4-Methoxybenzaldehyde

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Recently I am researching about INTRAMOLECULAR SCHMIDT REACTION; HYDROGEN-ATOM TRANSFER; PHOTOREDOX CATALYSIS; UNACTIVATED ALKENES; CYCLIC IMINES; ALKYL AZIDES; FUNCTIONALIZATION; PHOTOCATALYSIS; HYDROIMINATION; CONSTRUCTION, Saw an article supported by the European Research Council (ERC-CoG) [647550, 861930]; Spanish GovernmentSpanish GovernmentEuropean Commission [RTI2018-095038-B-I00]; Comunidad de MadridComunidad de Madrid; European Structural Funds [S2018/NMT-4367]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Rodriguez, RI; Mollari, L; Aleman, J. The CAS is 123-11-5. Through research, I have a further understanding and discovery of 4-Methoxybenzaldehyde. Recommanded Product: 123-11-5

Herein, a light-driven, atom-economical process that provides access to enantiomerically enriched substituted chiral 1-pyrroline derivatives is introduced. The strategy involves the distal functionalization of acyl heterocycles through a hydrogen-atom transfer (HAT) process and the use of tailor-made ketimines as reliable electrophilic partners. This transformation is translated into an enantiomerically controlled radical/polar cascade reaction in which water is produced as the sole by-product and stereoselectivity is dictated by coordination to a chiral-at-rhodium catalyst.

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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles