In 2021.0 MACROMOLECULES published article about CONFORMATIONAL STABILIZER; IMIDE)S; STEREOREGULARITY; POLYMERS; ETHER)S; NMR in [Lv, Jinghuang; Li, Ya] Shanghai Univ Engn Sci, Coll Chem & Chem Engn, Shanghai 201620, Peoples R China; [Lv, Jinghuang; Chen, Si; Xu, Zhenchuang; Zhang, Siquan; Zhao, Yanchuan] Chinese Acad Sci, Ctr Excellence Mol Synth, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China; [Zhao, Yanchuan] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Energy Regulat Mat, Shanghai 200032, Peoples R China in 2021.0, Cited 37.0. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5. Safety of 4-Methoxybenzaldehyde
Several diastereoisomeric polyesters bearing vicinal stereogenic centers in the backbone were synthesized to investigate the influence of diastereoisomerism on the properties of polymers. To hamper the free rotation of the C-sp(3)-C-sp(3) single bond between the stereogenic centers, bisphenol monomers containing vicinal CF3 moieties were designed and synthesized, wherein the CF3 group acts not only as a conformational stabilizer but also as a probe to provide information on stereoconfiguration. X-ray single-crystal structure and density functional theory (DFT) calculations indicate that the antimonomer tends to adopt a linear and extended configuration, whereas the most stable conformation for its diastereoisomer is kinked. These geometries resemble those possessed by the E and Z 1,2-disubstituted alkenes. The polymers based on these isomeric monomers display distinct glass transition state temperature (T-g), crystallinities, mesoscopic morphology, and hydrophobicity, which can be attributed to the different polymer chain arrangement in the solid state. These observations support our hypothesis to utilize aliphatic moieties bearing vicinal stereogenic centers to mimic the geometry of the E and Z olefinic units, which serves as a new strategy to finely tune the polymer
Safety of 4-Methoxybenzaldehyde. Bye, fridends, I hope you can learn more about C8H8O2, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles