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An article Thermo-Promoted Reactions of Anthranils with Carboxylic Acids, Amines, Phenols, and Malononitrile under Catalyst-Free Conditions WOS:000459367100035 published article about C-H AMINATION; BOND; QUINAZOLINONES; DERIVATIVES; INHIBITORS; ACCESS; 2,1-BENZISOXAZOLES; BENZOXAZINONES; REARRANGEMENT; HETEROCYCLES in [Jiang, Jing; Cai, Xin; Hu, Yanwei; Zhane, Shilei] Soochow Univ, Jiangsu Key Lab Neuropsychiat Dis, 199 Renai Rd, Suzhou 215123, Jiangsu, Peoples R China; [Jiang, Jing; Cai, Xin; Hu, Yanwei; Zhane, Shilei] Soochow Univ, Coll Pharmaceut Sci, 199 Renai Rd, Suzhou 215123, Jiangsu, Peoples R China; [Jiang, Jing; Zhang, Yinan] Nanjing Univ Chinese Med, Jiangsu Key Lab Funct Subst Chinese Med, Coll Pharm, Nanjing 210023, Jiangsu, Peoples R China; [Wang, Shun-Yi] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China; [Wang, Shun-Yi] Soochow Univ, Collaborat Innovat Ctr Suzhou Nano Sci & Technol, Suzhou 215123, Peoples R China; [Liu, Xuejun; Chen, Xiaodong] Shanghai Fosun Shino Tech Pharmaceut Co Ltd, Bldg 7,1999 ZhangHeng Rd, Shanghai 201203, Peoples R China in 2019.0, Cited 67.0. Recommanded Product: 99-93-4. The Name is 4′-Hydroxyacetophenone. Through research, I have a further understanding and discovery of 99-93-4

A convenient and atom-economical procedure for the thermo-promoted reactions of anthranil with different substrates was developed. The catalyst-free process affords various useful building blocks with good to moderate yields. This chemistry enables several step- and cost-effective approaches for biologically interesting molecules and provides an efficient platform for the investigation of untapped reactions at high temperature.

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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles