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Elemental iodine catalyzed decarboxylative sulfenylation (mono- or di) of electron-rich alkoxybenzoic acids using benzenesulfonohydrazides as sulfenylating agent for the synthesis of diaryl sulfides under transition metal-free conditions has been described. The method also works for the decarboxylative thioarylation (mono- or di) of indole carboxylic acids. Reactions showed very good functional group tolerance and excellent yields of sulfinylated products.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles