Mrdjan, GS; Matijevic, BM; Vastag, GG; Bozic, AR; Marinkovic, AD; Milcic, MK; Stojiljkovic, IN in [Mrdjan, Gorana S.; Matijevic, Borko M.; Vastag, Gyongyi Gy] Univ Novi Sad, Fac Sci, Dept Chem Biochem & Environm Protect, Trg Dositeja Obradovica 3, Novi Sad 21000, Serbia; [Bozic, Aleksandra R.] Belgrade Polytech, Brankova 17, Belgrade 11000, Serbia; [Marinkovic, Aleksandar D.] Univ Belgrade, Fac Technol & Met, Karnegijeva 4, Belgrade 11000, Serbia; [Milcic, Milos K.] Univ Belgrade, Fac Chem, Studentski Trg 12-16, Belgrade 11000, Serbia; [Stojiljkovic, Ivana N.] Univ Belgrade, Fac Forestry, Kneza Viseslava 1, Belgrade 11000, Serbia published Synthesis, solvent interactions and computational study of monocarbohydrazones in 2020.0, Cited 43.0. Formula: C7H6O2. The Name is 3-Hydroxybenzaldehyde. Through research, I have a further understanding and discovery of 100-83-4.
Carbohydrazones are compounds that are increasingly studied due to their wide potential biological activity. Monocarbohydrazones (mCHs), as one of the carbohydrazone derivatives, so far have been poorly investigated. For a more detailed study, in this paper, eighteen compounds of monocarbohydrazones (eight known and ten newly synthesized derivatives) were synthesized and characterized using NMR and IR spectroscopy. As carbohydrazones show E/Z isomerization caused by the presence of the imino group, some of the synthesized mCHs are in the form of a mixture of these two isomers. The effects of specific and nonspecific solvent-solute interactions on the UV absorption maxima shifts were evaluated using linear free energy relationships principles, i.e., using Kamlet-Taft’s and Catalan’s models. For more information about interactions between dissolved substance and the surrounding medium, correlations have been made with Hansen’s solubility parameters. The influence of the structure on the spectral behavior of the compounds tested was interpreted using Hammett’s equation. Experimentally obtained physicochemical properties of mCHs were compared to and confirmed with computational methods that included TD-DFT calculations and MP2 geometry optimizations. Graphic abstract
Formula: C7H6O2. About 3-Hydroxybenzaldehyde, If you have any questions, you can contact Mrdjan, GS; Matijevic, BM; Vastag, GG; Bozic, AR; Marinkovic, AD; Milcic, MK; Stojiljkovic, IN or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles