Synthetic Route of C4H10Cl2NiO2. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Nickel(II) chloride ethylene glycol dimethyl ether complex, is researched, Molecular C4H10Cl2NiO2, CAS is 29046-78-4, about Reactions of Late First-Row Transition Metal (Fe-Zn) Dichlorides with a PGeP Pincer Germylene. Author is Arauzo, Ana; Cabeza, Javier A.; Fernandez, Israel; Garcia-Alvarez, Pablo; Garcia-Rubio, Ines; Laglera-Gandara, Carlos J..
The reactivity of the PGeP germylene 2,2′-bis(di-isopropylphosphanylmethyl)-5,5′-dimethyldipyrromethane-1,1′-diylgermanium(II), Ge(pyrmPiPr2)2CMe2, with late first-row transition metal (Fe-Zn) dichlorides has been investigated. All reactions led to PGeP pincer chloridogermyl complexes. The reactions with FeCl2 and CoCl2 afforded paramagnetic square planar complexes of formula [MCl{κ3P,Ge,P-GeCl(pyrmPiPr2)2CMe2}] (M = Fe, Co). While the iron complex maintained an intermediate spin state (S1; μeff = 3.0μB) over the temperature range 50-380 K, the effective magnetic moment of the cobalt complex varied linearly with temperature from 1.9μB at 10 K to 3.6μB at 380 K, indicating a spin crossover behavior that involves S1/2 (predominant at T<180 K) and S3/2 (predominant at T>200 K) species. Both cobalt(II) species were detected by ESR at T<20 K. The reaction of Ge(pyrmPiPr2)2CMe2 with [NiCl2(dme)] (dme = dimethoxyethane) gave a square planar nickel(II) complex, [NiCl{κ3P,Ge,P-GeCl(pyrmPiPr2)2CMe2}], whereas the reaction with CuCl2 involved a redox process that rendered a mixture of the germanium(IV) compound GeCl2(pyrmPiPr2)2CMe2 and a binuclear copper(I) complex, [Cu2{μ-κ3P,Ge,P-GeCl(pyrmPiPr2)2CMe2}2], whose metal atoms are in tetrahedral environments. The reaction of the germylene with ZnCl2 led to the tetrahedral derivative [ZnCl{κ3P,Ge,P-GeCl(pyrmPiPr2)2CMe2}]. Although many compounds look similar to this compound(29046-78-4)Synthetic Route of C4H10Cl2NiO2, numerous studies have shown that this compound(SMILES:COCCOC.Cl[Ni]Cl), has unique advantages. If you want to know more about similar compounds, you can read my other articles.
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Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
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