Application In Synthesis of m-Methoxyphenol. In 2021.0 J ORG CHEM published article about CINNAMIC ACID-ESTERS; FUNGAL 17-BETA-HYDROXYSTEROID-DEHYDROGENASE; INTERNAL ALKYNES; DIPHENYLCYCLOPROPENONE; DERIVATIVES; INHIBITORS; COMPLEXES; CLEAVAGE; QSAR in [Nanda, Tanmayee; Biswal, Pragati; Pati, Bedadyuti Vedvyas; Banjare, Shyam Kumar] HBNI, Natl Inst Sci Educ & Res NISER, Bhubaneswar 752050, Odisha, India; [Ravikumar, Ponneri Chandrababu] HBNI, Natl Inst Sci Educ & Res NISER, Sch Chem Sci, Bhubaneswar 752050, Odisha, India in 2021.0, Cited 91.0. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6.
Strain-driven palladium/N-heterocyclic carbene-catalyzed C-C bond activation of diphenylcyclopropenone (DPC) has been explored for one-step access to trisubstituted alpha,beta-unsaturated esters and amides. The designed transformation works under mild conditions providing exclusively a single stereoisomer. Mechanistic studies support the oxidative addition of the C-C bond of cyclopropenone to in-situ-generated Pd(0) intermediate. We have proved that vinylic hydrogen in the product is coming from phenol/aniline through deuterium-labeling studies. Late-stage functionalization of bioactive molecules such as procaine, estrone, and hymecromone demonstrates the robustness of this protocol.
Application In Synthesis of m-Methoxyphenol. About m-Methoxyphenol, If you have any questions, you can contact Nanda, T; Biswal, P; Pati, BV; Banjare, SK; Ravikumar, PC or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles