Let¡¯s face it, organic chemistry can seem difficult to learn, Name: 2,4-Bis(2-phenylpropan-2-yl)phenol, Especially from a beginner¡¯s point of view. Like 2772-45-4, Name is 2,4-Bis(2-phenylpropan-2-yl)phenol, molecular formula is indole-building-block, belongs to indole-building-block compound. In a document, author is German Mejia-Hernandez, Francisco, introducing its new discovery.
Mechanochemical synthesis, linear and nonlinear optical properties of a new oligophenyleneimine with indole terminal moiety for optoelectronic application
A quadrupolar D-pi-A-pi-D oligophenyleneimine with indole moiety as terminal group (OIC-I) obtained by a green method of mechanosynthesis was obtained. The molecular structure of OIC-I was elucidated by FTIR and H1 NMR spectroscopies. DFT and TDDFT studies show possible intramolecular charge transfer (ICT) processes and a hyperpolarizability value that suggest a nonlinear behavior, which was verified by Z-scan technique. The linear optical characterization of OIC-I using UV-Vis spectroscopy and fluorescence in solution and solid state exhibits a bathochromic effect by increasing the polarity of the solvent. According to data obtained by the Z-scan technique, OIC-I could be used as a saturable absorb material, and this feature can be applied in nonlinear signal filtering, optical signal processing, and mode locking devices. OIC-I has attractive linear and nonlinear optical properties, good processability in solution, and thermal stability for its potential application as a saturated absorber in optoelectronic devices.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles