Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Zhang, Xing, once mentioned the application of 83-67-0, Name is 3,7-Dimethyl-3,7-dihydro-1H-purine-2,6-dione, molecular formula is C7H8N4O2, molecular weight is 180.164, MDL number is MFCD00022830, category is indole-building-block. Now introduce a scientific discovery about this category, Safety of 3,7-Dimethyl-3,7-dihydro-1H-purine-2,6-dione.
Metal-Free Blue-Light-Mediated Cyclopropanation of Indoles by Aryl(diazo)acetates
Blue-light-mediated cyclopropanation of indoles with aryl(diazo)acetates has been developed. The salient features of this strategy are that it is metal-free, operationally simple and atom-efficient, and that it uses an environmentally friendly energy source. In this protocol, blue light was employed as the sole energy source for the transformation. A variety of cyclopropane-fused indoline compounds was obtained in moderate to excellent yields and high diastereoselectivities under mild conditions.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles