Name: Benzyl Alcohol. In 2019 ACS SUSTAIN CHEM ENG published article about CARBON-DIOXIDE; CHEMICAL FIXATION; CYCLIC CARBONATES; QUANTITATIVE P-31; 2D NMR; CO2; LIGNOSULFONATE; EPOXIDES; DEPOLYMERIZATION; HYDROGENOLYSIS in [Guo, Li; Dou, Rui; Wu, Yaqi; Wang, Yang; Gong, Zhichao; Chen, Jialing; Wu, Xiaoqin] Wuhan Univ Sci & Technol, Key Lab Hubei Prov Coal Convers & New Carbon Mat, Sch Chem & Chem Engn, Heping Ave 947, Wuhan 430081, Hubei, Peoples R China; [Zhang, Ran] Huazhong Univ Sci & Technol, Key Lab Mol Biophys MOE, Coll Life Sci & Technol, Luoyu Rd 1037, Wuhan 430074, Hubei, Peoples R China; [Wang, Lei] Hubei Univ Technol, Hubei Prov Key Lab Green Mat Light Ind, Sch Mat & Chem Engn, Nanli Rd 28, Wuhan 430068, Hubei, Peoples R China in 2019, Cited 37. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
Lignin, as a byproduct from the paper industry and biorefineries, has been used as a renewable alternative to the conventional catalyst for future industrial application. However, due to the complex structure of lignin, its application has been considerably restricted. Herein, three types of lignin (soda lignin, kraft lignin, and enzymatic hydrolysis lignin) were prepared to illuminate the real impact of lignin interunit linkages and types of hydroxyl groups on the catalytic activity of cycloaddition reaction. Among these lignin/cocatalyst systems, a soda lignin/KI system showed excellent catalytic performance for the cycloaddition reaction at a low KI loading of 0.33 mol % (TON = 273). Particularly, soda lignin with abundant beta-O-4′ linkages, higher aliphatic C-a-OH groups, and phenolic hydroxyl groups as well as enriched carboxylic-OH groups could activate epoxides more efficiently and furthermore accelerate the cycloaddition reaction. Moreover, the dimeric intermolecular hydrogen bonding was dominant in soda lignin, which could also account for the higher catalytic activity of cycloaddition reaction. This work highlights the application of the soda lignin in a cycloaddition reaction and opens a new way for the utilization of lignin.
Name: Benzyl Alcohol. About Benzyl Alcohol, If you have any questions, you can contact Guo, L; Dou, R; Wu, YQ; Zhang, R; Wang, L; Wang, Y; Gong, ZC; Chen, JL; Wu, XQ or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles