A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 122111-03-9, Name is Gemcitabine hydrochloride, molecular formula is C9H12ClF2N3O4. In an article, author is Reddy, Chada Raji,once mentioned of 122111-03-9, Computed Properties of https://www.ambeed.com/products/122111-03-9.html.
This study describes the first carbon centered radical cyclization of N-propargyl indoles involving decarboxylation of alpha-keto acids in the presence of an Ag-catalyst. The present cascade carbon-carbon bond formation reactions provide C-acylated pyrrolo[1,2-a]indoles in good yields (25 examples). The amount of oxidant has a profound effect on the reaction to convert either the di-acylated products using 8 equiv. of K2S2O8 or mono-acylated products using 2 equiv. of K2S2O8. N-Propargyl pyrroles are also found to be suitable for delivering the corresponding 3H-pyrrolizines.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles