Recently I am researching about ALKENE HYDROGENATION; GRIGNARD-REAGENTS; COBALT; METAL; TEMPERATURE; SCOPE, Saw an article supported by the European Research CouncilEuropean Research Council (ERC)European Commission [CoG 683150]; University of Hamburg. Product Details of 80-59-1. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Bernauer, J; Wu, GJ; Jacobi von Wangelin, A. The CAS is 80-59-1. Through research, I have a further understanding and discovery of (E)-2-Methylbut-2-enoic acid
An iron-catalysed allylation of organomagnesium reagents (alkyl, aryl) with simple allyl acetates proceeds under mild conditions (Fe(OAc)(2) or Fe(acac)(2), Et2O, r.t.) to furnish various alkene and styrene derivatives. Mechanistic studies indicate the operation of a homotopic catalyst. The sequential combination of such iron-catalysed allylation with an iron-catalysed hydrogenation results in overall C(sp(3))-C(sp(3))-bond formation that constitutes an attractive alternative to challenging direct cross-coupling protocols with alkyl halides.
Product Details of 80-59-1. About (E)-2-Methylbut-2-enoic acid, If you have any questions, you can contact Bernauer, J; Wu, GJ; Jacobi von Wangelin, A or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles