Reference of 66-84-2, As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 66-84-2, Name is Glucosamine hydrochloride, SMILES is O=C[C@H](N)[C@@H](O)[C@H](O)[C@H](O)CO.Cl, belongs to indole-building-block compound. In a article, author is Deng, Yong, introduce new discover of the category.
Electrochemical Regioselective Phosphorylation of Nitrogen-Containing Heterocycles and Related Derivatives
The site-selective functionalization of biologically important nitrogen-containing heterocycles and related derivatives remains a challenging and important task. We report herein on the direct regiodivergent N1/C2 phosphorylation of free indole derivatives. Cyclic voltammograms and EPR data indicate that by utilizing different electrolyte-mediated anodic oxidation to generate different active indole species, a diverse collection of N1 and C2 phosphorylation products could be obtained in moderate to high yields under exogenous-oxidant-free and metal-catalyst-free electrochemical conditions. In addition, N-P coupling was also found to be compatible with various alkylamines.
Reference of 66-84-2, Each elementary reaction can be described in terms of its molecularity, the number of molecules that collide in that step. The slowest step in a reaction mechanism is the rate-determining step.you can also check out more blogs about 66-84-2.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles