Product Details of 2208-59-5. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: 2-(Pyridin-4-yl)-1H-benzo[d]imidazole, is researched, Molecular C12H9N3, CAS is 2208-59-5, about fac-Re(CO)3 core-based complex featuring benzimidazole as pendant motif from hydroxyquinoline and pyridylbenzimidazole. Author is Priyatharsini, Maruthupandiyan; Mishra, Isha; Shankar, Bhaskaran; Srinivasan, Navaneethakrishnan; Krishnakumar, Rajaputi Venkatraman; Sathiyendiran, Malaichamy.
Neutral heteroleptic acyclic complex, fac-[Re(CO)3(OQN)(pybimz)] (1), possessing free benzimidazole motif remotely is reported. The complex was obtained from 8-hydroxyquinoline (HOQN), 2-(4′-pyridyl)benzimidazole (pybimz), and Re2(CO)10. The structure of 1 was confirmed using single crystal x-ray diffraction (SCXRD) anal. The crystal structure of 1 is stabilized by various types of intermol. noncovalent interactions (π(OqN) ···π(OqN), NHĈH(pybimz)···O(OqN)-Re, and C-H(pybimz)···O≃C-Re). The extended H-bonding contacts between the mols. (C-H(pybimz)···O≃C-Re) in the crystal structure result in the cavity containing polymeric network structure in which toluene mols. reside. The solvent toluene mols. occupy ∼35% of the unit cell volume of the crystal. The absorption properties of the complex was studied both exptl. and theor.
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