Recommanded Product: Nickel(II) chloride ethylene glycol dimethyl ether complex. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Nickel(II) chloride ethylene glycol dimethyl ether complex, is researched, Molecular C4H10Cl2NiO2, CAS is 29046-78-4, about Ligand-based H2 transfer with dihydrazonopyrrole complexes of nickel. Author is McNeece, Andrew J.; Jesse, Kate A.; Filatov, Alexander S.; Schneider, Joseph E.; Anderson, John S..
Biol. uses precise control over proton, electron, H-atom, or H2 transfer to mediate challenging reactivity. While synthetic complexes have made incredible strides in replicating secondary coordination electron or proton donors, there are comparatively fewer examples of ligands that can mediate both proton and electron storage. Rarer still are ligands that can store full H2 equivalent Here we report a dihydrazonopyrrole Ni complex where an H2 equiv can be stored on the ligand periphery without any redox change at the metal center. This ligand-based storage of H2 can be leveraged for catalytic hydrogenations. Kinetic and computational anal. suggests a rate determining H2 binding step followed by comparatively facile H-H scission to hydrogenate the ligand. This system is an unusual example where a synthetic system can mimic biol.’s ability to mediate H2 transfer via secondary coordination sphere-based processes.
In addition to the literature in the link below, there is a lot of literature about this compound(Nickel(II) chloride ethylene glycol dimethyl ether complex)Recommanded Product: Nickel(II) chloride ethylene glycol dimethyl ether complex, illustrating the importance and wide applicability of this compound(29046-78-4).
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles