Dual Role of MoS2 Quantum Dots in a Cross-Dehydrogenative Coupling Reaction was written by Jaiswal, Komal;Girish, Yarabahally R.;Behera, Pradipta;De, Mrinmoy. And the article was included in ACS Organic & Inorganic Au in 2022.Formula: C8H6N2O2 This article mentions the following:
Modern day research focuses on the development of greener and eco-friendlier protocols to fabricate biol. relevant targets with minimal waste generation. C-C bond formation reactions are of prime importance in this regard. In a typical photocatalytic hydrogen evolution reaction (HER) three components are used, viz, catalyst, photosensitizer and sacrificial amine donor. Among these, the photosensitizer and sacrificial amine donors are wasted at the end of the reaction. Considering these drawbacks, in this work, we have developed a methodol. targeted at the utilization of sacrificial amine donors for C-H functionalization with MoS2 Quantum Dots (QDs) as the catalyst as well as photosensitizer. QDs indeed emerged to be an active participant in heterogeneous electron transfer (HET) process. This concept opens up new possibilities in the field of nanomaterial-based photomediated organic transformations without the aid of any external photosensitizers via a clean and sustainable protocol with no side product. In the experiment, the researchers used many compounds, for example, 6-Nitro-1H-indole (cas: 4769-96-4Formula: C8H6N2O2).
6-Nitro-1H-indole (cas: 4769-96-4) belongs to indole derivatives. The indole subunit is an almost ubiquitous component of biologically active natural products, and its study has been the focus of research for decades. Indole plays a fundamental role for QS in E. coli, being one of the signal molecules responsible for the transcription of a variety of genes (gabT, and tnaB ASTD). Formula: C8H6N2O2
Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles