On January 31, 1982, Kaneko, Chikara; Fujii, Harue; Kawai, Shinji; Hashiba, Kazuhiko; Karasawa, Yoshio; Wakai, Masue; Hayashi, Reiko; Somei, Masanori published an article.Reference of Methyl 2-methyl-1H-indole-3-carboxylate The title of the article was Studies on the N-oxides of 蟺-deficient N-heteroaromatics. XXXVI. Studies on oxazepine derivatives. XII. Photochemical and thermal Michael reactions of alcohols with methyl 2-phenyl-3,1-benzoxazepine-5-carboxylate and its derivatives. And the article contained the following:
Irradiation (鈮?00 nm) of Me 2-phenyl-3,1-benzoxazepine-5-carboxylate in an alc. afforded Z-2-BzNHC6H4C(:COR)CO2Me (I, R = Me, Et, CHMe2, CMe3, allyl) as the major addition product. In contrast, thermal reaction of the oxazepine with a primary alc. in the presence of NEt3 led to the exclusive formation of E-I. Similar addition products were also obtained stereoselectively from 3,1-benzoxazepines having an acetyl group at the 5-position. E-I and Z-I were equilibrated photochem. and the stereochem. of the two isomers was determined by 1H-NMR. An explanation is proposed for the stereoselectivities observed in the photochem. and thermal reactions. The experimental process involved the reaction of Methyl 2-methyl-1H-indole-3-carboxylate(cas: 65417-22-3).Reference of Methyl 2-methyl-1H-indole-3-carboxylate
The Article related to phenylbenzoxazepine carboxylate alcoholysis photochem thermal, benzoxazepinecarboxylate alcoholysis thermal photochem, benzamidophenylacrylate alkoxy isomer, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Esters, Acyl Peroxides, Acyl Halides and other aspects.Reference of Methyl 2-methyl-1H-indole-3-carboxylate
Referemce:
Indole alkaloid derivatives as building blocks of natural products from聽Bacillus thuringiensis聽and聽Bacillus velezensis聽and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles