Application In Synthesis of 4-Methoxybenzaldehyde. Authors Xie, YW; Zhao, ZN; Lin, ZW; Wang, YH; Liu, YQ; Huang, YY in ROYAL SOC CHEMISTRY published article about in [Xie, Yi-Wen; Zhao, Zhen-Ni; Lin, Zi-Wei; Wang, Yu-Hao; Liu, Ya-Qun; Huang, Yi-Yong] Wuhan Univ Technol, Sch Chem Chem Engn & Life Sci, Dept Chem, Wuhan 430070, Peoples R China in 2021, Cited 47. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5
The Petasis reaction using (1S,2R)-1-amino-2-indanol as the substrate and an activator to construct alpha- and beta-butadienyl amines in optically pure forms was realized, which are otherwise difficult to prepare. The reactions feature a metal-free nature, broad substrate scope, complete regioselectivities (gamma-selectivity of pinacol homoallenyl- and isoprenylboronates), and high to excellent chirality induction (up to >20 : 1 dr). The favored nucleophilic addition across the Si-face of the imine intermediate was explained using DFT calculations of the six-membered chair-like transition state.
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Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles