An article Serendipitous one-pot synthesis of chiral dienes from pyranosidic 2,4-bistriflates WOS:000659025300002 published article about SUGAR BUILDING-BLOCKS; RARE-SUGAR; BACTERIAL; ACCESS in [Rai, Diksha; Sanapala, Someswara Rao; Kulkarni, Suvarn S.] Indian Inst Technol, Dept Chem, Mumbai 400076, Maharashtra, India in 2021.0, Cited 16.0. The Name is Mequinol. Through research, I have a further understanding and discovery of 150-76-5. Recommanded Product: 150-76-5
Attempted nucleophilic displacements of L-rhamnosyl 2,4-bistriflates led to serendipitous formation of a chiral diene via competing cascade eliminations. The reaction also followed the same pathway with D-rhamnosyl and Dmannosyl 2,4-bistriflates substrates providing access to dienes with opposite stereochemistry. The reaction presumably proceeds through E2 elimination of C2 triflate followed by allylic rearrangement. The easily accessible chiral dienes would be useful in the synthesis of natural products.
Recommanded Product: 150-76-5. About Mequinol, If you have any questions, you can contact Rai, D; Sanapala, SR; Kulkarni, SS or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles