Authors Wang, K; Zhang, L; Tang, WJ; Sun, HM; Xue, D; Lei, M; Xiao, JL; Wang, C in WILEY-V C H VERLAG GMBH published article about N-HETEROCYCLIC CARBENE; CATALYZED BETA-ALKYLATION; METHODOLOGY COOPERATIVE CATALYSIS; TRANSFER HYDROGENATION; SECONDARY ALCOHOLS; BORROWING-HYDROGEN; ENANTIOSELECTIVE FUNCTIONALIZATION; ALLYLIC ALCOHOLS; C-ALKYLATION; COMPLEXES in [Wang, Kun; Tang, Weijun; Sun, Huaming; Xue, Dong; Xiao, Jianliang; Wang, Chao] Shaanxi Normal Univ, Sch Chem & Chem Engn, Key Lab Appl Surface & Colloid Chem, Minist Educ, Xian 710062, Peoples R China; [Zhang, Lin; Lei, Ming] Beijing Univ Chem Technol, Inst Computat Chem, Coll Chem, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China; [Xiao, Jianliang] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, England in 2020.0, Cited 156.0. Computed Properties of C7H8O. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
The first example of an asymmetric Guerbet reaction has been developed. Using commercially available, classic Noyori Ru-II-diamine-diphosphine catalysts, well-known in asymmetric hydrogenation, racemic secondary alcohols are shown to couple with primary alcohols in the presence of a base, affording new chiral alcohols with enantiomeric ratios of up to 99:1. Requiring no reducing agents, the protocol provides an easy, alternative route for the synthesis of chiral alcohols. Mechanistic studies reveal that the reaction proceeds via a Ru-catalyzed asymmetric hydrogen autotransfer process in concert with a base-promoted allylic alcohol isomerization.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles