On October 31, 2009, Luo, Ren-Shi; Weng, Jiang; Ai, Hui-Bing; Lu, Gui; Chan, Albert S. C. published an article.Application In Synthesis of H-Idc-OH The title of the article was Highly efficient asymmetric Michael reaction of aldehydes to nitroalkenes with diphenylperhydroindolinol silyl ethers as organocatalysts. And the article contained the following:
New dihydroindole and perhydroindole derivatives were synthesized in good yields and evaluated as chiral catalysts in the asym. Michael reaction of aldehydes to nitroalkenes. (2S,3aS,7aS)-Diphenylperhydroindolinol silyl ether facilitated the reaction of a wide range of aldehyde and nitroalkene substrates, providing Michael adducts in nearly optically pure form (99% ee), good yields and high diastereoselectivities (syn/anti up to 99:1). These results show that perhydroindole derivatives can be highly efficient organocatalysts for the asym. Michael reaction, exhibiting comparable or even better enantioselectivities than proline derivatives The experimental process involved the reaction of H-Idc-OH(cas: 79815-20-6).Application In Synthesis of H-Idc-OH
The Article related to michael stereoselective aldehyde nitroalkene silyloxydiphenylmethylindole catalyst, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Aldehydes and Derivatives, Including Sulfur Analogs and other aspects.Application In Synthesis of H-Idc-OH
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Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles