Luo, Renshi et al. published their research in European Journal of Organic Chemistry in 2020 |CAS: 79815-20-6

The Article related to enantioselective reformatsky ketone iodoacetate chiral indolinylmethanol catalyst, General Organic Chemistry: Synthetic Methods and other aspects.SDS of cas: 79815-20-6

On July 27, 2020, Luo, Renshi; Chen, Miao-Miao; Ouyang, Lu; Chan, Albert S. C.; Lu, Gui published an article.SDS of cas: 79815-20-6 The title of the article was Enantioselective Reformatsky Reaction of Ketones Catalyzed by Chiral Indolinylmethanol. And the article contained the following:

A reliable and practical Reformatsky reaction of Et iodidoacetate with ketones for the synthesis of chiral β-hydroxyl carbonyl compounds in good yields and excellent enantioselectivities is presented. A readily available dihydroindole derivative was used as chiral catalyst, Et iodidoacetate was the nucleophile, and Me2Zn was the zinc source. The presence of air was found to be essential for the efficient construction of new carbon-carbon bonds through a radical pathway. The experimental process involved the reaction of H-Idc-OH(cas: 79815-20-6).SDS of cas: 79815-20-6

The Article related to enantioselective reformatsky ketone iodoacetate chiral indolinylmethanol catalyst, General Organic Chemistry: Synthetic Methods and other aspects.SDS of cas: 79815-20-6

Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles