Mitchell, Glynn et al. published their research in Journal of the Chemical Society, Chemical Communications in 1986 |CAS: 65417-22-3

The Article related to triazole photolysis mechanism, azirine intermediate triazole photolysis, Physical Organic Chemistry: Ring Formation, Cleavage, Enlargement, and Contraction and other aspects.Application of 65417-22-3

On March 1, 1986, Mitchell, Glynn; Rees, Charles W. published an article.Application of 65417-22-3 The title of the article was 1H-Azirines as intermediates in the photolysis of 1,2,3-triazoles. And the article contained the following:

Photolysis of triazoles I (R = 1-C10H7, R1 = H, R2 = CO2Et, CN; R1 = Me, R2 = CO2Me, CN) in MeCN gave the benzindoles II (R1, R2 as before) together with smaller amounts of the corresponding isomers III. Similarly, photolysis of I (R = Ph, R1 = H, Me, R2 = CO2Me) gave the rearranged products IV (R3 = CO2Me, R4 = H, Me) (V and VI, resp.) in 5 and 42% yield, resp., together with the isomeric IV (R3 = H, Me, R4 = CO2Me) in 25 and 21% yield, resp. Formation of II, V, and VI provides evidence for antiarom. 1H-azirines as reactive intermediates in a photochem. reaction. The experimental process involved the reaction of Methyl 2-methyl-1H-indole-3-carboxylate(cas: 65417-22-3).Application of 65417-22-3

The Article related to triazole photolysis mechanism, azirine intermediate triazole photolysis, Physical Organic Chemistry: Ring Formation, Cleavage, Enlargement, and Contraction and other aspects.Application of 65417-22-3

Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles