An article The Steric Effect in Green Benzylation of Arenes with Benzyl Alcohol Catalyzed by Hierarchical H-beta Zeolite WOS:000498266100085 published article about LIQUID-PHASE ALKYLATION; BENZENE; PERFORMANCE; DIFFUSION; CHLORIDE; KINETICS; TOLUENE; NITROAROMATICS; ADSORPTION; REDUCTION in [Liu, Xinyu; Lu, Meihuan; Wang, Xuan; Lu, Juyou; Yang, Jianxin] Hainan Univ, Lab Green Catalysis & React Engn Haikou, Hainan Prov Fine Chem Engn Res Ctr, Coll Sci,Key Lab Trop Biol Resources,Minist Educ, Haikou 570228, Hainan, Peoples R China in 2019, Cited 58. Recommanded Product: Benzyl Alcohol. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
For decades the steric effect was still ambiguously understood in catalytic benzylation reactions of arenes with benzyl alcohol, which limited the green synthesis of phenylmethane derivates in industrial scale. This research applies a series of silica-alumina beta zeolites to systematically evaluate factors like catalyst porosity, reactants molecule size, and reaction temperature on catalytic benzylation. First, a suitable hierarchical beta zeolite catalyst was screened out by X-ray powder diffraction, N-2 adsorption-desorption, and probe benzylation with p-xylene. In the following substrates expanding study, for a typical benzylation of benzene, it showed extraordinary performance among literature reported ones that the conversion was 98% while selectivity was 90% at 353 K only after 10 min. The steric effect of aromatics with different molecular sizes on benzylation was observed. The reaction activities of four different aromatics followed the order: benzene > toluene > p-xylene > mesitylene. Combined with macroscopic kinetic analysis, this comprehensive study points out for the first time that the nature of this steric effect was dominated by the relative adsorption efficiency of different guest aromatic molecules on the host zeolite surface.
About Benzyl Alcohol, If you have any questions, you can contact Liu, XY; Lu, MH; Wang, X; Lu, JY; Yang, JX or concate me.. Recommanded Product: Benzyl Alcohol
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles