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Enamine rearrangement of pyridinium salts: Part X – Novel synthesis of indole ring

beta-Nicotyrinium salts (2) undergo ring opening and recyclization reaction when heated with aq. alkyl amine or sodium hydroxide to give indole derivatives (4).

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Reference£º
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles