Quality Control of Benzyl Alcohol. In 2020.0 CATAL TODAY published article about METAL-ORGANIC FRAMEWORK; GOLD NANOPARTICLES; NANOPOROUS CARBON; ROOM-TEMPERATURE; EFFICIENT; CO; NITROGEN; SURFACE; SIZE; NANOCLUSTERS in [Chen, Fengfeng; Lu, Qingwen; Fan, Ting; Fang, Ruiqi; Li, Yingwei] South China Univ Technol, Sch Chem & Chem Engn, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Peoples R China in 2020.0, Cited 50.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
Here we report a novel approach to synthesize Au NPs immobilized on N-doped carbon materials. In this strategy, an ionic liquid (IL) [Bmim][AuCl4] was selected as the precursor for Au NPs and porous framework of ZIF-8 as the host for the IL. Raman spectroscopy, transmission electron microscopy, N-2 physical absorption and Fourier infrared spectra confirmed that the IL was successfully incorporated in the ZIF-8 pores. Followed by a thermal treatment under inert atmosphere, highly dispersed Au NPs were obtained and stabilized by nitrogen species from the carbonization of organic ligand in the metal-organic frameworks (MOFs). The [Bmim][AuCl4]@ ZIF-8-6.25%-T materials exhibited high catalytic activity for the selective aerobic oxidation of alcohols, affording excellent yields (up to > 99%) under atmospheric air and base-free conditions. Catalytic reaction along with catalyst characterization results revealed a strong interaction between Au NPs and N species. TEM, XRD and XPS characterization results further suggested that the N species could not only prevent the Au NPs from aggregation, but also further enhance the reaction activity.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles