Mumtaz, Yasir; Liu, Jie published the artcile< Iodine-catalyzed Regioselective Electrophilic (Fluoroalkyl) Sulfenylation of Indoles with (RSO2)2O via Deoxygenative Reduction>, Category: indole-building-block, the main research area is indole sulfonic anhydride iodine catalyst regioselective sulfenylation deoxygenative reduction; thioindole preparation.
A method for electrophilic C-H sulfenylation by deoxygenative reduction from less expensive and easily available sulfonic anhydrides was reported. This C-S bond-forming reaction allowed a general access to sulfenyl electrophiles, including important trifluoromethyl, perfluoroalkyl and aryl derivatives that are otherwise difficult to afford. Under metal-free conditions, the reaction yielded 3-arylthio (fluoroalkylthio) indoles in good to excellent yields. The catalytic technique tolerated a wide range of functional groups.
Asian Journal of Organic Chemistry published new progress about Indoles Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 93247-78-0 belongs to class indole-building-block, and the molecular formula is C10H9NO2, Category: indole-building-block.
Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles