Sousa, SCA; Realista, S; Royo, B in [Sousa, Sara C. A.; Realista, Sara; Royo, Beatriz] Univ Nova Lisboa, Inst Tecnol Quim & Biol Antonio Xavier, ITQB NOVA, Oeiras, Portugal published Bench-Stable Manganese NHC Complexes for the Selective Reduction of Esters to Alcohols with Silanes in 2020.0, Cited 58.0. Name: Benzyl Alcohol. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
Selective reduction of esters to alcohols was accomplished through Mn(I)-mediated hydrosilylation reaction. The manganese tricarbonyl complex [Mn(bis-NHC)(CO)(3)Br] resulted an active pre-catalyst for the reduction of a variety of esters using phenylsilane and the cheap and readily available polymethylhydrosiloxane. Anin situexamination of the catalytic reaction using(55)Mn NMR spectroscopy allowed us to detect the formation of Mn(I) intermediate active species.
Name: Benzyl Alcohol. About Benzyl Alcohol, If you have any questions, you can contact Sousa, SCA; Realista, S; Royo, B or concate me.
Reference:
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,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles