I found the field of Chemistry very interesting. Saw the article Divergent Synthesis of Substituted Amino-1,2,4-triazole Derivatives published in 2021.0. Formula: C8H8O2, Reprint Addresses Li, JQ; Qin, ZH (corresponding author), China Agr Univ, Dept Chem, Coll Sci, Innovat Ctr Pesticide Res, Beijing 100193, Peoples R China.. The CAS is 123-11-5. Through research, I have a further understanding and discovery of 4-Methoxybenzaldehyde
A divergent efficient assembly of disubstituted 1,2,4-triazoles was established by cyclization of readily accessible N’-nitro-2-hydrocarbylidene-hydrazinecarboximidamides with moderate to excellent yields under mild reaction conditions. This divergent synthetic strategy was achieved simply by varying the reaction conditions. Under acidic conditions, amino-1,2,4-triazoles were obtained by an intramolecular redox reaction involving the NO2 group. Control experiments and DFT studies revealed that this transformation proceeds via an intramolecular 1,3-hydride transfer pathway leading to HNO2 elimination. Under neutral conditions with water as the solvent, nitroimino-1,2,4-triazoles were obtained by oxidative intramolecular annulation under air.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles